Bundesliga bottom side Darmstadt slipped closer to an immediate relegation back to the second division after a 1-0 home defeat by Freiburg, a league record 22nd game without a win. Later on Sunday, Bayer Leverkusen can seal their first Bundesliga title with a win at home to Werder Bremen. Ritsu Doan’s well-taken goal for Freiburg in the first half meant Darmstadt stayed 13 points away from absolute safety with just five matchdays left. Third-bottom Mainz, in the relegation play-off spot, sit 12 points above the Lilies. Freiburg, in Christian Streich’s last season as coach, have still not given…